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  1. Chemical potential is a/an

  2. A.

     Extensive property

    B.

     Intensive property

    C.

     Force which drives the chemical system to equilibrium

    D.

     Both B and C

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  3. For a real gas, the chemical potential is given by

  4. A.

     RT dlnP

    B.

     RT dlnf

    C.

     R dlnf

    D.

     None of these

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  5. For an ideal gas, the chemical potential is given by

  6. A.

     RT dlnP

    B.

     R dlnP

    C.

     R dlnf

    D.

     None of these

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  7. Boiling of liquid is accompanied with increase in the

  8. A.

     Vapor pressure

    B.

     Specific Gibbs free energy

    C.

     Specific entropy

    D.

     All of the above

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  9. Law of corresponding states says that

  10. A.

     , two different gases behave similarly, if their reduced properties (i.e. P, V and T) are same

    B.

     The surface of separation (i. e. the meniscus) between liquid and vapour phase disappears at the critical temperature

    C.

     No gas can be liquified above the critical temperature, howsoever high the pressure may be

    D.

     The molar heat of energy of gas at constant volume should be nearly constant (about 3 calories)

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  11. Free energy, fugacity and activity co-efficient are all affected by change in the temperature. The fugacity co-efficient of a gas at constant pressure ____with the increase of reduced temperature.

  12. A.

     Decreases

    B.

     Increases

    C.

     Remains constant

    D.

     Decreases logarithmically

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  13. Any substance above its critical temperature exists as

  14. A.

     Saturated vapour

    B.

     Solid

    C.

     Gas

    D.

     Liquid

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  15. First law of thermodynamics is mathematically stated as

  16. A.

     dQ = dE + dW

    B.

     dQ = dE - dW

    C.

     dE = dQ + dW

    D.

     dW = dQ + dE

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  17. A cyclic engine exchanges heat with two reservoirs maintained at 100 and 300°C respectively. The maximum work (in J) that can be obtained from 1000 J of heat extracted from the hot reservoir is

  18. A.

     349

    B.

     651

    C.

     667

    D.

     1000

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  19. Cv for an ideal gas

  20. A.

     Does not depend upon temperature

    B.

     Is independent of pressure only

    C.

     Is independent of volume only

    D.

     Is independent of both pressure and volume

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