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  1. Free energy

  2. A.

     Decreases in all spontaneous (or irreversible) processes

    B.

     Change during a spontaneous process has a negative value

    C.

     Remains unchanged in reversible processes carried at constant temperature and pressure

    D.

     All of the above

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  3. Co-efficient of Performance (COP) of a refrigerator is the ratio of the

  4. A.

     Work required to refrigeration obtained

    B.

     Refrigeration obtained to the work required

    C.

     Lower to higher temperature

    D.

     Higher to lower temperature

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  5. The value of Joule-Thomson co-efficient, in case where cooling occurs after the throttling process is

  6. A.

     0

    B.

     ∞

    C.

     +ve

    D.

     -ve

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  7. Fugacity is a measure of the

  8. A.

     Escaping tendencies of the same substance in different phases of a system

    B.

     Relative volatility of a mixture of two miscible liquids

    C.

     Behaviour of ideal gases

    D.

     None of these

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  9. Fugacity is most helpful in

  10. A.

     Representing actual behaviour of real gases

    B.

     Representing actual behaviour of ideal gases

    C.

     The study of chemical equilibria involving gases at atmospheric pressure

    D.

     None of these

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  11. As the entropy of the universe is increasing, day by day, the work producing capacity of a heat engine is

  12. A.

     Not changed

    B.

     Decreasing

    C.

     Increasing

    D.

     Data sufficient, can't be predicted

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  13. Which of the following is not an equation of state?

  14. A.

     Bertholet equation

    B.

     Clausius Clayperon equation

    C.

     Beattie-Bridgeman equation

    D.

     None of these

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  15. Pick out the wrong statement.

  16. A.

     Minimum number of degree of freedom of a system is zero

    B.

     Degree of freedom of a system containing a gaseous mixture of helium, carbon dioxide and hydrogen is 4

    C.

     For a two phase system in equilibrium made up of four non-reacting chemical species, the number of degrees of freedom is 4

    D.

     Enthalpy and internal energy change is zero during phase change processes like melting, vaporisation and sublimation

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  17. Which of the following is Virial equation of state?

  18. A.

     (p + a/V²)(V - b) = nRT

    B.

     PV = nRT

    C.

     PV = A + B/V + C/V² + D/V³ + …

    D.

     None of the above

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  19. Which law of the thermodynamics provids basis for measuring the thermodynamic property?

  20. A.

     First law

    B.

     Zeroth law

    C.

     Third law

    D.

     Second law

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