Discussion :: Chemical Engineering Thermodynamics
- For an isothermal reversible compression of an ideal gas
Answer : Option C
Explanation :
Actually the internal energy (U) of a substance is a function of
dU=CvdT−[P+T((∂V∂T)p(∂V∂P)T)dV]For an ideal gas, PV=RTSo, (∂V∂T)p=RPand (∂V∂P)T=−RTP2Hence, dU=CvdT
Similarly we can prove dH=CpdT
So, enthalpy and internal energy are solely functions of temperature in case of ideal gas hence ΔE=ΔH=0
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