Discussion :: Chemical Engineering Thermodynamics
- Entropy change for an irreversible isolated system is
Answer : Option D
Explanation :
From second law of thermodynamics
TdS⩾δQ⇒TdS⩾dU+δW
For an irreversible process S−dU−δW>0. So, system undergoing irreversible change under constant internal energy and constant volume will have entropy change greater than zero dS>0.
And for an reversible process TdS−dU−δW=0.
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