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Chemical Engineering :: Stoichiometry

  1. Heat of neutralisation of a strong acid and strong base is always a constant value, i.e., 57 KJ/Kg mole. This is because

  2. A.
    the strong base and strong acid reacts completely.
    B.
    the salt formed does not hydrolyse.
    C.
    only OH- and H+ ions react in every case.
    D.
    the strong base and strong acid reacts in aqueous solution.

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  3. 1 gm mole of an alcohol whose molecular weight is 74 contains 48 gms of carbon, 10 gms of hydrogen and 16 gms of oxygen. Its molecular formula is

  4. A.
    C4H9OH
    B.
    C3H21OH
    C.
    (C2H4)2H2.OH
    D.
    C2H33OH

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  5. A solution with reasonably permanent pH is called a/an __________ solution.

  6. A.
    ideal
    B.
    non-ideal
    C.
    buffer
    D.
    colloidal

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  7. The value of Trouton's ratio (λb/Tb) for a number of substances is 21 (where, λb = molal that of vaporisation of a substance at its normal boiling point, KCal/kg. mole and Tb = normal boiling point, °K). The Kis-tyakowsky equation is used for calculation of Trouton's ratio of __________ liquids.

  8. A.
    polar
    B.
    non-polar
    C.
    both (a) & (b)
    D.
    neither (a) nor (b)

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  9. Pick out the wrong unit conversion of heat transfer rate.

  10. A.
    1 kcal/hr= 1.163 Watt.
    B.
    1 Watt = 1.163 kcal/hr.
    C.
    1 BTU/ft2.hr = 2.712 kcal/m2.hr.
    D.
    1 kcal/m2.hr = 0.3687 BTU/ft2.hr = 1.163 Watt/m2.

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  11. A gas at 0°C is cooled at constant pressure until its volume becomes half the original volume. The temperature of the gas at this state will be

  12. A.
    -136.5°C
    B.
    - 136.5°K
    C.
    -273°C
    D.
    0°K

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  13. Colligative properties of a dilute solution are those which depend entirely upon the

  14. A.
    constitution of the solute.
    B.
    chemical composition of the solute.
    C.
    number of solute molecules contained in a given volume of the solvent.
    D.
    none of these.

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  15. For an ideal solution, the total vapor pressure varies __________ with the composition(expressed as mole fraction).

  16. A.
    inversely
    B.
    exponentially
    C.
    linearly
    D.
    negligibly

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  17. Pick out the wrong statement.

  18. A.
    Atomic heat capacities of the crystalline solid elements are nearly constant and equal to 6.2 kcal/kg-atom according to the law of Petit and Dulong.
    B.
    Atomic heat capacities of all solid elements decrease greatly with decrease in temperature, approaching a value of zero at absolute zero temperature, when in the crystalline state.
    C.
    Generally, the heat capacities of compounds are lower in the liquid than in the solid state.
    D.
    The heat capacity of a heterogeneous mixture is an additive property, but when solutions are formed, this additive property may no longer exist.

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  19. Measurement of the amount of dry gas collected over water from volume of moist gas is based on the

  20. A.
    Charle's law.
    B.
    Dalton's law of partial pressures.
    C.
    Avogadro's hypothesis.
    D.
    Boyle's law.

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