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Chemical Engineering :: Chemical Reaction Engineering

  1. A second order reaction of the form A + B C is called a pseudo-first order reaction, when

  2. A.
    CA0 = CB0
    B.
    CA0 > CB0
    C.
    CB0 > CA0
    D.
    CB0CB0

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  3. Pick out the wrong statement.

  4. A.

    In a first order reaction, A products; the reaction becomes slower as it proceeds, because the concentration of A decreases and the rate is proportional to the concentration of A.

    B.

    Transition state theory approaches the problem of calculating reaction rates by concentrating on the idea of activated complexes.

    C.

    According to the penetration theory, the mass transfer co-efficient decreases, if the exposure time of an eddy to the solute decreases.

    D.

    If the rate of an irreversible reaction, A + B 2C is k.CA.CB, then the reaction is always elementary.


  5. Effectiveness factor (E) of a catalyst pellet is defined as, Effectiveness factor for a first order reaction is given by (where, T = Thiele modulus)

  6. A.
    tan hT/T
    B.
    tan T/T
    C.
    tan hT/tan T
    D.
    none of these

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  7. Inversion of cane sugar is an example of

  8. A.
    unimolecular reaction with first order.
    B.
    bimolecular reaction with second order.
    C.
    bimolecular reaction with first order.
    D.
    unimolecular reaction with second order.

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  9. Pick out the correct statement.

  10. A.
    A catalyst speeds up the forward reaction but slows shown the reverse reaction.
    B.
    Addition of catalyst changes the equilibrium constant.
    C.
    Pressure changes do not change the equilibrium concentrations.
    D.
    The composition of equilibrium is changed by catalyst.

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  11. In which of the following gaseous phase reactions, the equilibrium of the reaction remains unaffacted by pressure changes ?

  12. A.
    2O3 3O2
    B.
    N2 + O2 2NO
    C.
    2NO2 N2O4
    D.
    2SO2 + O2 2SO3

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  13. The mean conversion in the exit stream, for a second order, liquid phase reaction in a non-ideal flow reactor is given by

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  15. Integral method for analysing the kinetic data is used

  16. A.
    when the data are scattered.
    B.
    for testing specific mechanisms with simple rate expressions.
    C.
    both (a) and (b).
    D.
    none of these.

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  17. Concentration of the limiting reactant (with initial concentration of a moles/litre) after time t is (a-x). Then 't' for a first order reaction is given by

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  19. The rate of a gas phase reaction is given by K . CA . CB. If the volume of the reaction vessel is reduced to l/4th of its initial volume, then the reaction rate compared to the original rate will be __________ times.

  20. A.
    4
    B.
    16
    C.
    8
    D.
    2

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