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Chemical Engineering :: Chemical Reaction Engineering

  1. For a heterogenous catalytic reaction, A + B → C, with equimole feed of A and B, the initial rate - rA0 is invariant with total pressure. The rate controlling step is

  2. A.

     Surface Kc/(1 + TS) reaction between absorbed A and B in the gas phase

    B.

     Surface reaction between absorbed A and absorbed B

    C.

     Surface reaction between A in the gas phase and absorbed B

    D.

     Desorption of C

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  3. In an ideal P.F.R. at steady state conditions

  4. A.

     The composition of reactants remains constant along a flow path

    B.

     The conversion of the reactant varies from point to point along a flow path

    C.

     There is no lateral mixing of fluid

    D.

     There may be diffusion along the flow path

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  5. Pick the WRONG design guideline for a reactor in which the reactions, A → R (desired) and A → S (undesired) are to take place. The ratio of the reaction rates is rR/rS = (k₁/k₂).Csub>Aa-b

  6. A.

     Use high pressure and eliminate inerts, when a > b

    B.

     Avoid recycle, when a > b

    C.

     Use batch reactor or plug flow reactor, when a > b

    D.

     Use CSTR with a high conversion, when a > b

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  7. The value of steric factor 'P' in the equation k = PZeE/RT usually ranges from

  8. A.

     L.0 to 10⁻⁸

    B.

     L.l.to 10²

    C.

     0.1 to 0.9

    D.

     None of these

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  9. Helium-mercury method can be used to determine the __________ of the catalyst particle.

  10. A.

     Pore volume

    B.

     Solid density

    C.

     Porosity

    D.

     All of the above

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  11. An exothermic reaction takes place in an adiabatic reactor. The product temperature __________ reactor feed temperature.

  12. A.

     Is always equal to

    B.

     Is always greater than

    C.

     Is always less than

    D.

     May be greater or less than

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  13. Bulk diffusion in catalyst pore __________ with increase in pressure.

  14. A.

     Increases

    B.

     Decreases

    C.

     Remains unchanged

    D.

     Increases exponentially

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  15. Chemical kinetics can predict the __________ of a chemical reaction.

  16. A.

     Rate

    B.

     Feasibility

    C.

     Both A & B

    D.

     Neither A nor B

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  17. The size of plug flow reactor (PFR) for all positive reaction orders and for any given duty, is __________ that of mixed reactor.

  18. A.

     Greater than

    B.

     Equal to

    C.

     Smaller than

    D.

     Unpredictable from the data

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  19. B.E.T. method can be used to determine the __________ of a porous catalyst.

  20. A.

     Solid density

    B.

     Pore volume

    C.

     Surface area

    D.

     All of the above

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